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MSDS Number: S7466 * * * * * Effective Date: 04/03/06 * * * * * Supercedes: 11/10/05
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Sudan IV (C.I. 26105)
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1. Product Identification
Synonyms: Oil red; 2-Naphthalenol, 1-[[2-methyl-4-[(2-methylphenyl)azo]phenyl]azo]-
CAS No.: 85-83-6
Molecular Weight: 380.45
Chemical Formula: C24H20ON4
Product Codes:
J.T. Baker: V141
Mallinckrodt: E067
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2. Composition/Information on Ingredients
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------------ ---------
Sudan IV 85-83-6 90 - 100% Yes
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3. Hazards Identification
Emergency Overview
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WARNING! IRRITANT. CAUSES IRRITATION TO EYES, RESPIRATORY SYSTEM AND SKIN. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. HANDLE IN A FUME HOOD. THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN THOROUGHLY INVESTIGATED.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
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Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 2 - Moderate (Life)
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Green (General Storage)
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Potential Health Effects
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Inhalation:
Irritation of mucous membranes.
Ingestion:
Stomach pains vomiting, diarrhea.
Skin Contact:
Irritation, May be absorbed through the skin with possible systemic effects.
Eye Contact:
Irritation, with discomfort, tearing.
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.
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4. First Aid Measures
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Prompt action is essential.
Ingestion:
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Thorough cleansing of the entire contaminated area of the body including scalp and nails is of the utmost importance.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention.
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5. Fire Fighting Measures
Fire:
Not expected to be a fire hazard.
Explosion:
Emits toxic fumes under fire conditions.
Fire Extinguishing Media:
Use water spray, carbon dioxide, dry chemical powder or appropriate foam.
Special Information:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece operated in positive pressure mode. The protective clothing should prevent contact with skin and eyes.
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6. Accidental Release Measures
Evacuate area. Wear self-contained breathing apparatus, rubber boots and heavy rubber gloves. Wear disposable coveralls and discard them after use. Sweep up, place in a bag, and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.
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7. Handling and Storage
Keep container tightly closed. Store in cool, dry, well-ventilated area away from heat, sparks, or flame. Handling operations should be conducted in a chemical fume hood. Do not add any other material to the container. Do not wash down the drain. Do not allow smoking and food consumption while handling. Do not get in eyes, on skin, or on clothing. Wash thoroughly after use. Since empty container retains product residue, follow label warnings even after container is empty.
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8. Exposure Controls/Personal Protection
Airborne Exposure Limits:
None established.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to the substance is apparent and engineering controls are not feasble, consult an industrial hygienist. For emergencies, or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
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9. Physical and Chemical Properties
Appearance:
Dark brown Crystalline solid.
Odor:
No information found.
Solubility:
Negligible (< 0.1%)
Specific Gravity:
No information found.
pH:
No information found.
% Volatiles by volume @ 21C (70F):
N/A
Boiling Point:
No information found.
Melting Point:
No information found.
Vapor Density (Air=1):
Not applicable.
Vapor Pressure (mm Hg):
Not applicable.
Evaporation Rate (BuAc=1):
No information found.
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10. Stability and Reactivity
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Oxides of nitrogen, carbon monoxide, carbon dioxide.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Strong oxidizing agents.
Conditions to Avoid:
Heat, dusting, moisture.
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11. Toxicological Information
Investigated as a tumorigen and mutagen.
--------\Cancer Lists\------------------------------------------------------
---NTP Carcinogen---
Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Sudan IV (85-83-6) No No 3
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12. Ecological Information
Environmental Fate:
No information found.
Environmental Toxicity:
No information found.
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13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
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14. Transport Information
Not regulated.
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15. Regulatory Information
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Sudan IV (85-83-6) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Sudan IV (85-83-6) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Sudan IV (85-83-6) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Sudan IV (85-83-6) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: No
SARA 311/312: Acute: No Chronic: No Fire: No Pressure: No
Reactivity: No (Pure / Solid)
Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.
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16. Other Information
NFPA Ratings: Health: 2 Flammability: 1 Reactivity: 0
Label Hazard Warning:
WARNING! IRRITANT. CAUSES IRRITATION TO EYES, RESPIRATORY SYSTEM AND SKIN. HARMFUL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. HANDLE IN A FUME HOOD. THE TOXICOLOGICAL PROPERTIES OF THIS MATERIAL HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Label Precautions:
Avoid ALL contact.
Avoid breathing dust. Keep in tightly closed container. Use with adequate ventilation. Wash thoroughly after handling. In case of fire, use appropriate foam, dry chemical, or carbon dioxide. In case of spill, sweep up and remove. Flush spill area with water.
Label First Aid:
If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Prompt action is essential. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3, 11, 16.
Disclaimer:
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Mallinckrodt Baker, Inc. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. MALLINCKRODT BAKER, INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.) MSDS
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