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Polyethylene glycol 300 Polyglycol E-300 Polyethylene Glycol 300 H(OCH2CH2)nOH or (C2-H4-O)n-H2-O Not available. TQ3630000 25322-68-3 PO108 Not available. SPECTRUM LABORATORY PRODUCTS INC. 14422 S. SAN PEDRO STREET GARDENA, CA 90248 CALL (310) 516-8000 SPECTRUM LABORATORY PRODUCTS INC. 14422 S. SAN PEDRO STREET GARDENA, CA 90248 1 0 0 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment Section 1. Chemical Product and Company Identification Common Name/ Trade Name Catalog Number(s). CAS# RTECS CI# Manufacturer Synonym Chemical Name Chemical Family IN CASE OF EMERGENCY CHEMTREC (24hr) 800-424-9300 Chemical Formula Supplier See Section 15. Commercial Name(s) PEG-6 TSCA T S C A 8 ( b ) i n v e n t o r y : Polyethylene glycol 300 1 1 0 Health Hazard Fire Hazard Reactivity Page Number: 1 Polyethylene glycol 300: ORAL (LD50): Acute: 27500 mg/kg [Rat]. 31000 mg/kg [Mouse]. DERMAL (LD50): Acute: >20000 mg/kg [Rabbit]. 1) Polyethylene glycol 300 25322-68-3 100 Toxicological Data on Ingredients Name Section 2.Composition and Information on Ingredients Exposure Limits TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by Weight CAS # Slightly hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition. Section 3. Hazards Identification Potential Acute Health Effects Potential Chronic Health Effects Continued on Next Page Polyethylene glycol 300 Page Number: 2 Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Not available. If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Not available. Not available. Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Inhalation Serious Inhalation Ingestion Serious Ingestion Not available. May be combustible at high temperature. These products are carbon oxides (CO, CO2). OPEN CUP: 199°C (390.2°F). Not available. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Slightly flammable to flammable in presence of heat. Not available. Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Not available. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 6. Accidental Release Measures Small Spill Large Spill Continued on Next Page Polyethylene glycol 300 Page Number: 3 Keep container tightly closed. Keep container in a cool, well-ventilated area. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents. Section 7. Handling and Storage Precautions Storage Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Safety glasses. Synthetic apron or Lab coat. Gloves (impervious). Respiratory Protection: Adequate general room ventilation or local exhaust ventiliation is sufficient for normal handling at room temperature. Also, respiratory protection is not necessary for normal handling at room temperature since exposure to vapor is minimal due to low vapor pressure. If room ventilation is inadequate and/or if handling of material generates airborne concentrations of mist or vapor above the recommended exposure guidelines, a vapor respirator may be necessary. Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. TWA: 10 (mg/m3) from AIHA Consult local authorities for acceptable exposure limits. Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits >200°C (392°F) Liquid. ( viscous) Not available. Not available. -15°C (5°F) - -8 C(18 F) 1.125 - 1.127 (Water = 1) >10 (Air = 1) <0 kPa (@ 20°C) Not available. Not available. See solubility in water. Easily soluble in cold water, hot water. Not available. Not available. 285 - 315 (avg. 300) g/mole Odorless. Not available. Clear Section 9. Physical and Chemical Properties Physical state and appearance Odor Taste Color Molecular Weight pH (1% soln/water) Boiling Point Melting Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility Continued on Next Page Polyethylene glycol 300 Page Number: 4 The product is stable. Non-corrosive in presence of glass. Reactive with oxidizing agents. Not available. Slightly Hygroscopic Not available. Incompatible materials (strong oxidizing agents), dust generation, excess heat. Section 10. Stability and Reactivity Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity Special Remarks on Reactivity Special Remarks on Corrosivity Polymerization Will not occur. Absorbed through skin. Eye contact. Acute oral toxicity (LD50): 27500 mg/kg [Rat]. Acute dermal toxicity (LD50): >20000 mg/kg [Rabbit]. Slightly hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation. Not available. Not available. Acute Potential Health Effects: Skin: May cause mild skin irritation. It can be absorbed through the skin. Eyes: May cause mild, temporary eye irritation. Corneal injury is unlikely. Inhalation: Low hazard. At room temperature, exposure to vapor is minimal due to low volatility (vapor pressure). If product is heated, inhalation of vapor may cause respiratory tract irritation. Ingestion: Low hazard. Low toxicity. May cause gastrointestinal tract irritation which may include nausea and vomiting. May affect urinary system. Chronic Potential Health Effects: Chronic occupational exposure is mainly limited to dermal contact. Prolonged or repeated contact may cause delayed eczematous and immediate uticarial reactions, and contact dermatitis. Ingestion: Prolonged or repeated ingestion may affect urinary system (kidney, ureter, or bladder), liver, metabolism(weight loss). This product contains trace amounts of the following which may cause cancer: Acetaldehyde (<=0.0006%) 1,4-Dioxane (<=0.0005%) Formaldehyde (<=0.0004%) Ethylene Oxide (0.0005%) This product contains tract amounts of the following which may cause reproductive harm: Ethylene Oxide (<0.0005%) Section 11. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Special Remarks on Toxicity to Animals Special Remarks on Chronic Effects on Humans Special Remarks on other Toxic Effects on Humans Ecotoxicity in water (LC50): >5000 mg/l 24 hours [Goldfish]. Not available. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are less toxic than the product itself. Section 12. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation Continued on Next Page Polyethylene glycol 300 Page Number: 5 Not available. Special Remarks on the Products of Biodegradation Section 13. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. DOT Classification Not a DOT controlled material (United States). Not applicable. Not applicable. Section 14. Transport Information Identification DOT (Pictograms) Special Provisions for Transport EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No. 500-038-2). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. 0 1 0 1 1 0 C Not controlled under WHMIS (Canada). This product is not classified according to the EU regulations. Section 15. Other Regulatory Information and Pictograms Other Regulations Other Classifications WHMIS (Canada) DSCL (EEC) HMIS (U.S.A.) Health Hazard Fire Hazard Reactivity National Fire Protection Association (U.S.A.) Personal Protection Health Flammability Reactivity Specific hazard Federal and State Regulations California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Acetaldehyde; 1,4-Dioxane; Formaldehyde; Ethylene Oxide California prop. 65: This product contains the following ingredients for which the State of California has found to cause reproductive harm (female) which would require a warning under the statute: Ethylene Oxide California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Acetaldehyde; 1,4-Dioxane; Formaldehyde; Ethylene Oxide Minnesota: Polyethylene glycol 300 TSCA 8(b) inventory: Polyethylene glycol 300 California Proposition 65 Warnings California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: Acetaldehyde; 1,4-Dioxane; Formaldehyde; Ethylene Oxide California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. Not applicable. Continued on Next Page Polyethylene glycol 300 Page Number: 6 WHMIS (Canada) (Pictograms) DSCL (Europe) (Pictograms) TDG (Canada) (Pictograms) ADR (Europe) (Pictograms) Protective Equipment Not applicable. Synthetic apron. Safety glasses. Gloves. Not available. Not available. CALL (310) 516-8000 All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein. Notice to Reader Verified by Sonia Owen. Printed 9/13/2006. Validated by Sonia Owen on 8/11/2006. Other Special Considerations References Section 16. Other Information MSDS Code P3981

MSDS

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