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Ethanol, 190 Proof, FCC ** CLICK ITEM FOR SIZES AND PRICES****: BC Scientific
FREE SHIPPING $500.00 OR MORE CODE FSHIP12.
NO CHEMICALS/GLASSWARE1.800.967.5316
Ethanol, 190 Proof, FCC ** CLICK ITEM FOR SIZES AND PRICES****
Quantity in Basket:
none Code: E1020
Price:$0.00
100ML $15.70
500ML $45.75
6X 500ML $139.50
1L $45.50
4X4L $479.00
200 L BULK $4800.00
Promotion Code:
Quantity:
E1020
Ethanol, 190 Proof, FCC
Ethanol, Undenatured; Ethyl Alcohol; Alcohol
C2H5OH F.W. 46.07 64-17-5
Assay (C2H5OH; by Volume) Min. 94.9%
MAXIMUM LIMITS
Acidity (as Acetic Acid) 0.003%
Alkalinity (as Ammonia) 3 mg/kg
Fusel Oil To pass test
Ketones, Isopropyl Alcohol To pass test
Lead 0.5 mg/kg
Methanol To pass test
Nonvolatile Residue 0.003%
Solubility in Water To pass test
Substances Darkened by Sulfuric Acid To pass test
Substances Reducing Permanganate To pass test
Shipping Information
DOT: Ethanol, 3, UN1170, PG II
70 lb
Ethyl Alcohol 190 Proof
Ethanol 190 Proof
Not available
Not applicable.
Aliphatic glycol or alcohol (Solvent.)
Not applicable.
Mixture.
E1020, E1029,E1421, ET108
Not applicable.
SPECTRUM LABORATORY PRODUCTS INC.
14422 S. SAN PEDRO STREET
GARDENA, CA 90248
3
2 0
Material Safety Data Sheet MSDA MSDS MSDS MSDS MSDS*****************
NFPA HMIS Personal Protective Equipment
Section 1. Chemical Product and Company Identification
Common Name/
Trade Name
Catalog
Number(s).
CAS#
RTECS
CI#
Manufacturer
Synonym
Chemical Name
Chemical Family
IN CASE OF EMERGENCY
CHEMTREC (24hr) 800-424-9300
Chemical Formula
Supplier
See Section 15.
Commercial Name(s) Not available.
TSCA TSCA 8(b) inventory: Water;
Ethyl alcohol 200 Proof
2
3
0
Health Hazard
Fire Hazard
Reactivity
Page Number: 1
Ethyl alcohol 200 Proof:
ORAL (LD50): Acute: 7060 mg/kg [Rat]. 3450 mg/kg [Mouse].
VAPOR (LC50): Acute: 20000 ppm 8 hours [Rat]. 39000 mg/m3 4 hours [Mouse].
1) Water 7732-18-5 5
2) Ethyl alcohol 200 Proof 64-17-5 1900 95
Toxicological Data
on Ingredients
Name
Section 2.Composition and Information on Ingredients
Exposure Limits
TWA (mg/m3) STEL (mg/m3) CEIL (mg/m3) % by Weight CAS #
Hazardous in case of skin contact (irritant), of eye contact (irritant), . Slightly hazardous in case of skin contact
(permeator), of ingestion. Non-corrosive for skin. Non-corrosive to the eyes. Non-corrosive for lungs.
Slightly hazardous in case of skin contact (sensitizer)
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof].
Classified A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof].
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for
bacteria and/or yeast. [Ethyl alcohol 200 Proof].
TERATOGENIC EFFECTS: Classified PROVEN for human [Ethyl alcohol 200 Proof].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 200 Proof]. Classified
Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof].
The substance is toxic to blood, the reproductive system, liver, upper respiratory tract, skin, central nervous
Section 3. Hazards Identification
Potential Acute Health Effects
Potential Chronic Health
Effects
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 2
system (CNS).
Repeated or prolonged exposure to the substance can produce target organs damage.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if
symptoms appear.
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
keeping eyelids open. Cold water may be used. Get medical attention.
In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove
contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes
before reuse. Get medical attention.
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical
attention.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention if symptoms appear.
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.
Not available.
Section 4. First Aid Measures
Eye Contact
Skin Contact
Serious Skin Contact
Inhalation
Serious Inhalation
Ingestion
Serious Ingestion
The lowest known value is 363°C (685.4°F) (Ethyl alcohol 200 Proof).
Flammable.
These products are carbon oxides (CO, CO2).
CLOSED CUP: 18.5°C (65.3°F).(estimated)
The greatest known range is LOWER: 3.3% UPPER: 19% (Ethyl alcohol 200 Proof)
Flammable liquid, soluble or dispersed in water.
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use alcohol foam, water spray or fog.
Highly flammable in presence of open flames and sparks, of heat.
Slightly flammable to flammable in presence of oxidizing materials.
Non-flammable in presence of shocks.
Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel
considerable distance to source of ignition and flash back. May form explosive mixtures with air.
Contact with Bromine pentafluoride is likely to cause fire or explosion.
Ethanol ignites on contact with chromyl chloride.
Ethanol ignites on contact with iodine heptafluoride gas.
It ignites than explodes upon contact with nitrosyl perchlorate.
Additon of platinum black catalyst caused ignition.
(Ethyl alcohol 200 Proof)
Slightly explosive in presence of open flames and sparks, of heat, of oxidizing materials, of acids.
Non-explosive in presence of shocks.
Ethanol has an explosive reaction with the oxidized coating around potassium metal.
Ethanol ignites and then explodes on contact with acetic anhydride + sodium hydrosulfate (ignites and may
explode), disulfuric acid + nitric acid, phosphorous(III) oxide platinum, potassium-tert-butoxide+ acids.
Ethanol forms explosive products in reaction with the following
compound : ammonia + silver nitrate (forms silver nitride and silver fulminate), iodine + phosphorus (forms ethane
iodide), magnesium perchlorate (forms ethyl perchlorate), mercuric nitrate, nitric acid + silver (forms silver
fulminate) silver nitrate (forms ethyl nitrate) silver(I) oxide + ammonia or hydrazine (forms
silver nitride and silver fulminate), sodium (evolves hydrogen gas).
Sodium Hydrazide + alcohol can produce an explosion.
Section 5. Fire and Explosion Data
Flammability of the Product
Auto-Ignition Temperature
Flash Points
Flammable Limits
Products of Combustion
Fire Hazards in Presence of
Various Substances
Explosion Hazards in Presence
of Various Substances
Fire Fighting Media
and Instructions
Special Remarks on
Fire Hazards
Special Remarks on Explosion
Hazards
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 3
Alcohols should not be mixed with mercuric nitrate, as explosive mercuric fulminate may be formed.
May form explosive mixture with manganese perchlorate + 2,2-dimethoxypropane.
Addition of alcohols to highly concentrate hydrogen peroxide forms powerful explosives.
Explodes on contact with calcium hypochlorite
Vapor may explode if ignited in an enclosed area.
Containers may explode when heated or involved in a fire.
Vapors may form explosive mixtures with air.
(Ethyl alcohol 200 Proof)
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal
container.
Flammable liquid.
Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,
sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or
confined areas; dike if needed. Be careful that the product is not present at a concentration level above TLV.
Check TLV on the MSDS and with local authorities.
Section 6. Accidental Release Measures
Small Spill
Large Spill
Store in a segregated and approved area. Keep container in a cool, well-ventilated area. Keep container tightly
closed and sealed until ready for use. Avoid all possible sources of ignition (spark or flame).
Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not
ingest. Do not breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient
ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the
container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents,
acids, alkalis, moisture.
Section 7. Handling and Storage
Precautions
Storage
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their
respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the
work-station location.
Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be
used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Ethyl alcohol 200 Proof
TWA: 1900 (mg/m3) from OSHA (PEL) [United States]
TWA: 1000 (ppm) from OSHA (PEL) [United States]
TWA: 1900 (mg/m3) from NIOSH [United States]
TWA: 1000 (ppm) from NIOSH [United States]
TWA: 1000 (ppm) [United Kingdom (UK)]
TWA: 1920 (mg/m3) [United Kingdom (UK)]
TWA: 1000 STEL: 1250 (ppm) [Canada]
Consult local authorities for acceptable exposure limits.
Section 8. Exposure Controls/Personal Protection
Engineering Controls
Personal Protection
Personal Protection in Case of
a Large Spill
Exposure Limits
The lowest known value is 78.5°C (173.3°F) (Ethyl alcohol 200 Proof). Weighted average: 79.58°C (175.2°F)
Liquid.
Neutral.
May start to solidify at -114.1°C (-173.4°F) based on data for: Ethyl alcohol 200 Proof.
Not applicable.
Alcohol like. Mild to strong. Like wine or
whiskey; Ethereal, vinous. Pleasant.
Burning. Pungent.
Clear Colorless.
Section 9. Physical and Chemical Properties
Physical state and appearance Odor
Taste
Color
Molecular Weight
pH (1% soln/water)
Boiling Point
Melting Point
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 4
Not available.
Weighted average: 0.8 (Water = 1)
The highest known value is 1.59 (Air = 1) (Ethyl alcohol 200 Proof). Weighted average: 1.54 (Air = 1)
The highest known value is 5.7 kPa (@ 20°C) (Ethyl alcohol 200 Proof). Weighted average: 5.53 kPa (@ 20°C)
Not available.
Not available.
See solubility in water, methanol, diethyl ether, acetone.
Easily soluble in cold water, hot water, methanol, diethyl ether.
Soluble in acetone.
100 ppm
The lowest known value is 243°C (469.4°F) (Ethyl alcohol 200 Proof). Critical Temperature
Specific Gravity
Vapor Pressure
Vapor Density
Volatility
Odor Threshold
Water/Oil Dist. Coeff.
Ionicity (in Water)
Dispersion Properties
Solubility
The product is stable.
Non-corrosive in presence of glass.
Reactive with oxidizing agents, metals, acids, alkalis.
Not available.
Ethanol rapidly absorbs moisture from the air.
Can react vigorously with oxiders.
The following oxidants have been demonstrated to undergo vigorous/explosive reaction with ethanol: barium
perchlorate, bromine pentafluoride, calcium hypochlorite, chlorate, chloryl perchlorate, chromium trioxide, chromyl
chloride, dioxygen difluoride, disulfuryl difluoride, fluorine nitrate, hydrogen peroxide, iodine heptafluoride, nitric
acid, nitrosyl perchlorate, perchloric acid, permanganic acid, peroxodisulfuric acid, potassium dioxide, potassium
perchlorate, potassium permanganate, ruthenium(VIII) oxide, silver perchlorate, silver peroxide, uranium
hexafluoride, uranyl perchlorate, chlorine.
Ethanol reacts violently/expodes with the following compounds: acetyl bromide (evolves hydrogen bromide)
acetyl chloride, aluminum sesquibromide ethylate, active metals, aluminum, alkali metals, isocyanates, halogens,
hydazine, caustics (ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide),
acid anhydrides, ammonia or hyrazine + silver oxide, chlorate, chromic anhydride, cyanuric acid + water,
dichloromethane + sulfuric acid + nitrate (or) nitrite, hydrogen peroxide + sulfuric acid, iodine + phosphorus,
iodine + methanol + mercuric oxide, magnesium perchlorate, manganese perchlorate + 2,2-dimethoxy propane,
perchlorates, chromates, permanganates + sulfuric acid, potassium superoxide, potassium tert-butoxide, silver &
nitric acid, silver perchlorate, sodium hydrazide, sulfuric acid + sodium dichromate, tetrachlorisilane + water,
mercuric nitrate, acetic anhydride + sodium hydrosulfate, disulfuric acid + nitric acid, phosphorous (III0 oxide,
potassium tert-butoxide + acids.
Ethanol is also incompatible with platinium, and sodium.
No really safe conditions exist under which ethyl alcohol and chlorine oxides can be handled.
Reacts vigorously with acetyl chloride (Ethyl alcohol 200 Proof)
Not available.
Incompatible materials, heat, sources of ignition.
Section 10. Stability and Reactivity Data
Stability
Instability Temperature
Conditions of Instability
Incompatibility with various
substances
Corrosivity
Special Remarks on
Reactivity
Special Remarks on
Corrosivity
Polymerization Will not occur.
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 5
Absorbed through skin. Eye contact. Inhalation. Ingestion.
Acute oral toxicity (LD50): 3632 mg/kg (Mouse) (Calculated value for the mixture).
Hazardous in case of skin contact (irritant), of inhalation.
Slightly hazardous in case of skin contact (permeator), of ingestion.
CARCINOGENIC EFFECTS: Classified PROVEN by State of California Proposition 65 [Ethyl alcohol 200 Proof].
Classified A4 (Not classifiable for human or animal.) by ACGIH [Ethyl alcohol 200 Proof].
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. [Ethyl alcohol 200 Proof]. Mutagenic for
bacteria and/or yeast. [Ethyl alcohol 200 Proof].
TERATOGENIC EFFECTS: Classified PROVEN for human [Ethyl alcohol 200 Proof].
DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethyl alcohol 200 Proof]. Classified
Reproductive system/toxin/female, Reproductive system/toxin/male [POSSIBLE] [Ethyl alcohol 200 Proof].
Lowest Published Dose/Conc:
LDL[Human] - Route: Oral; Dose: 1400 mg/kg
LDL[Human child] - Route: Oral; Dose: 2000 mg/kg
LDL[Rabbit] - Route: Skin; Dose: 20000 mg/kg (Ethyl alcohol 200 Proof)
Acute potential health effects:
Skin: causes skin irritation
Eyes: causes eye irritation
Ingestion: May cause gastrointestinal tract irritation with nausea, vomiting, diarrhea, and alterations in gastric
secretions. May affect behavior/central nervous system (central nervous system depression - amnesia,
headache, muscular incoordination, excitation, mild euphoria, slurred speech, drowsiness, staggaring gait, fatigue,
changes in mood/personality, excessive talking, dizziness, ataxia, somnolence, coma/narcosis, hallucinations,
distorted perceptions, general anesthetic), peripherial nervous system (spastic paralysis)vision (diplopia).
Moderately toxic and narcotic in high concentrations. May also affect metabolism, blood, liver, respiration
(dyspnea), and endocrine system.
May affect respiratory tract, cardiovascular(cardiac arrhythmias, hypotension), and urinary systems.
Inhalation: May cause irritation of the respiratory tract and affect behavior/central nervous system with symptoms
similar to ingestion.
Chronic Potential Health Effects:
Skin: Prolonged or repeated skin contact may casue dermatitis, an allergic reaction.
Ingestion: Prolonged or repeated ingestion will have similiar effects as acute ingestion. It may also affect the
brain. (Ethyl alcohol 200 Proof)
May affect genetic material (mutagenic)
Causes adverse reproductive effects and birth defects (teratogenic) , based on moderate to heavy consumption.
May cause cancer based on animal data.
Human: passes through the placenta, excreted in maternal milk. (Ethyl alcohol 200 Proof)
Section 11. Toxicological Information
Routes of Entry
Toxicity to Animals
Chronic Effects on Humans
Other Toxic Effects on
Humans
Special Remarks on
Toxicity to Animals
Special Remarks on
Chronic Effects on Humans
Special Remarks on other
Toxic Effects on Humans
Not available.
Not available.
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
The product itself and its products of degradation are not toxic.
Not available.
Section 12. Ecological Information
Ecotoxicity
BOD5 and COD
Products of Biodegradation
Toxicity of the Products
of Biodegradation
Special Remarks on the
Products of Biodegradation
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 6
Section 13. Disposal Considerations
Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental
control regulations.
DOT Classification CLASS 3: Flammable liquid.
Not available.
: Ethanol (Ethyl alcohol 200 Proof) UNNA: 1170 PG: II
Section 14. Transport Information
Identification
DOT (Pictograms)
Special Provisions for
Transport
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
0
3
2
2
3
0
h
CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F).
CLASS D-2B: Material causing other toxic effects (TOXIC).
R11- Highly flammable.
Section 15. Other Regulatory Information and Pictograms
Other Regulations
Other Classifications WHMIS (Canada)
DSCL (EEC)
HMIS (U.S.A.) Health Hazard
Fire Hazard
Reactivity
National Fire Protection
Association (U.S.A.)
Personal Protection
Health
Flammability
Reactivity
Specific hazard
Federal and State
Regulations
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Ethyl
alcohol 200 Proof (in alcoholic beverage)
California prop. 65: This product contains the following ingredients for which the State of California has found to
cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof (in alcoholic
beverage)
Connecticut hazardous material survey.: Ethyl alcohol 200 Proof
Illinois toxic substances disclosure to employee act: Ethyl alcohol 200 Proof
Rhode Island RTK hazardous substances: Ethyl alcohol 200 Proof
Pennsylvania RTK: Ethyl alcohol 200 Proof
Florida: Ethyl alcohol 200 Proof
Minnesota: Ethyl alcohol 200 Proof
Massachusetts RTK: Ethyl alcohol 200 Proof
Massachusetts spill list: Ethyl alcohol 200 Proof
California Director's List of Hazardous Substances: Ethyl alcohol 200 Proof
New Jersey: Ethyl alcohol 200 Proof
TSCA 8(b) inventory: Water; Ethyl alcohol 200 Proof
California
Proposition 65
Warnings
California prop. 65: This product contains the following ingredients for which the State of California has found
to cause birth defects which would require a warning under the statute: Ethyl alcohol 200 Proof (in alcoholic
beverage)
S7- Keep container tightly closed.
S16- Keep away from sources of ignition - No
smoking.
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 7
3
WHMIS (Canada)
(Pictograms)
DSCL (Europe)
(Pictograms)
TDG (Canada)
(Pictograms)
ADR (Europe)
(Pictograms)
Protective Equipment
Vapor respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Lab coat.
Splash goggles.
Gloves.
Not available.
Not available.
CALL (310) 516-8000
Notice to Reader
Verified by Sonia Owen.
Printed 9/12/2006.
Validated by Sonia Owen on 8/11/2006.
Other Special
Considerations
References
Section 16. Other Information
MSDS Code E3285
Continued on Next Page
Ethyl Alcohol 190 Proof Page Number: 8
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper
methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products,
Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.